汤卫军 (Weijun Tang)

Associate Professor

School of Chemistry & Chemical Engineering, Shaanxi Normal University

E-Mail: tangwj@iccas.ac.cn

Research ID: D-9915-2011

Educational Background

2005.4–2008.10, Ph.D., Organic Chemistry, The Hong Kong Polytechnic University, Advisors: Prof. Albert Sun-Chi Chan, and Prof. Qing-Hua Fan

2001. 9–2004. 7, M.Sc., Organic Chemistry, Xiangtan University and Institute of Chemistry, Chinese Academy of Sciences  Advisors: Prof. Qing-Hua Fan and Prof. Nian-Fa Yang

1997. 9 – 2001. 7, B.Sc., Chemistry, Xiangtan University,

 

Research experience

2013. 1-present,  Postdoctoral Fellow with Prof. Guochen Jia, The Hong Kong University of Science & Technology, HK

2012. 11-2012. 12, Research Associate with Prof. Fuk-Yee Kwong, The Hong Kong PolytechnicUniversity, HK

2009. 10-2012. 9, Postdoctoral Associate with Prof. Jianliang Xiao University of Liverpool, UK

2009. 3-2009. 8, Research Associate with Prof. Albert S. C. Chan, The Hong Kong Polytechnic University, HK

2008.09-2009.02 Research Assistant with Professor Albert S. C. Chan, The Hong Kong Polytechnic University, HK

2004.08-2005.03 Research Assistant with Professor Qing-Hua Fan, Institute of Chemistry, Chinese Academy of Sciences, Beijing, CN

 

Awads

2006 The Prize for Excellent Master Thesis in Hunan Province, China

 

Representative Publications

8. Tang, W.J.; Johnston, S.; Li, C.Q.; Iggo, J.; Bacsa, J.; Xiao, J.L. "Cooperative Catalysis: Combing an Achiral Metal Catalyst with a Chiral Bronsted Acid to Enable Asymmetric Hydrogenation of Imines", Chem. Eur. J.  2013, 19, 14187-14193.                 

7. Tang, W.J.; Johnston, S.; Iggo, J. A.; Berry, N. G.; Phelan, M.; Lian, L.; Bacsa, J.; Xiao, J.L. "Cooperative catalysis through Noncovalent Interactions", Angew. Chem. Int. Ed. 2013, 52, 1668-1672.

6. Tang, W.J.; Sun, Y.W.; Xu, L.J.; Lam, K.H.; Fan, Q.H.; Albert S. C. Chan. "Highly Enantioselective Hydrogenation of Quinoline and Pyridine Derivatives with Chiral Ir-DifluorPhos Catalyst", Org. Biomol. Chem. 2010, 8, 3464-3471. 

5. Tang, W.J.; Tan, J.; Xu, L.J.; Lam, K.H.; Fan, Q.H.; Albert S. C. Chan. "Highly Enantioselective Hydrogenation of Quinoline and Pyridine Derivatives with Ir-(P-Phos) Catalyst", Adv. Synth. Catal. 2010, 352, 1055-1062.

4. Tang, W.J.;Xu, L.J.; Fan, Q.H.; Wang, J.; Fan, B.M.; Zhou, Z.Y.; Lam, K.H.; Albert S. C. Chan. "Asymmetric Hydrogenation of Quinoxalines with Diphosphinite Ligands: A Practical Synthesis of Enantioenriched, Substituted Tetrahydroquinoxalines", Angew. Chem. Int. Ed. 2009, 48, 9135-9138.

3. Tang, W.J.; Zhu, S.F.; Xu, L.J.; Zhou, Q.L.; Fan, Q.H.; Zhou, H.F.; Lam, K.H.; Albert S. C. Chan. "Asymmetric Hydrogenation of Quinolines with High Substrate/Catalyst Ratio", Chem. Commun. 2007, 613-615.

2. Tang, W.J.; Huang, Y.Y.; He, Y.M.; Fan, Q.H."Dendritic MonoPhos: synthesis and application in Rh-catalyzed asymmetric hydrogenation", Tetrahedron: Asymmetry. 2006, 17, 536–543.

1. Tang, W.J.; Yang, N.F.; Yi, B.; Deng, G.J.; Huang, Y.Y.; Fan, Q.H. "Phase selectively soluble dendrimer-bound osmium complex: a highly effective and easily recyclable catalyst for olefin dihydroxylation",Chem. Commun. 2004, 1378-1379. 

Papers with name

24. Vial-Macos, B.; Tang, W.J.; Wu, X.F.; Xiao, J.L. "A Highly Active Cyclometallated Iridium Catalyst for the Hydrogenation of imines." Org. Biomol. Chem. 2013, 11, 6934-6939.

23. Wu,J.J.;Tang,W.J.;Pettman, A.and Xiao, J.L. "Efficient and Chemoselective Reduction of Pyridines to Tetrahydropyridines and Piperidines via Rhodium-Catalyzed Transfer Hydrogenation", Adv. Synth. Catal. 2013, 355, 35-40. 

22. Jiang, Z.; Zhang, L.J.; Dong, C.N.; Cai, Z.Z.; Su, X.M.; Li, H.R.;Tang, W.J.; Xu, L.J.; Fan, Q.H. "Direct Synthesis of 8-Aryl Tetrahydroquinolines via Pd-catalyzed ortho Arylation of Aryl Ureas in Water", RSC Advances. 2013, 3, 1025-1028.

21. Jiang, Z.; Zhang, L.J.; Dong, C.N.; Cai, Z.Z.; Tang, W.J.; Li, H.R.; Xu, L.J.; Xiao, J.L. "Palladium-Catalyzed Highly Regioselective Arylation of Allylamines with Thiophenes and Furans", Adv. Synth. Catal. 2012, 354, 3225-3230. 

20. Wu,J.J.; Wang, C.; Tang,W.J.;Pettman, A.and Xiao, J.L., "The remarkable effect of simple ion: iodide promoted transfer hydrogenation of heteroaromatics", Chem. Eur. J. 2012, 18, 9525-9529.

19. Jiang, Z.; Zhang, L.J.; Dong, C.N.; Ma, B.D.; Tang, W.J.; Xu, L.J.; Fan, Q.H.; Xiao, J.L. "Palladium-catalyzed Highly Regioselective and Stereoselective Arylation of Electron-rich Allylamines with Aryl Bromides", Tetrahedron, 2012, 68, 4919-4926.

18. Deng, Y.H.; Jiang, Z.; Yao, M.; Xu, D.; Zhang, L.J.; Li, H.R.; Tang, W.J.; Xu, L.J. "Palladium-Catalyzed, Highly Efficient, Regiocontrolled Arylation of Electron-Rich Allylamines with Aryl Halides", Adv. Synth.  Catal. 2012, 354, 899-907.

17. Tan, J.; Tang, W.J.; Sun, Y.W.; Jiang, Z.; Chen, F.; Xu, ,L.J.; Fan, Q.H.; Xiao, J.L., "pH-Regulated transfer hydrogenation of quinoxalines with a Cp*Irediamine catalyst in aqueous media", Tetrahedron 2011, 67, 6206-6213.

16. Xu, L.J.; Yi, B.; Dang, L.M.; Tang, W.J. "Asymmetric Catalysis in Ionic Liquids", Progress in Chemistry, 2010, 22, 1254-1273.

15. Feng, L.C.; Sun, Y.W.; Tang, W.J.; Xu, L.J.; Lam, K.H.; Zhou, Z.Y. Albert S. C. Chan. "High efficient chemoselective construction of 2,2-dimethyl-6-substituted- 4-piperidones via multi-component tandem Mannich reaction in ionic liquids", Green Chem. 2010, 12, 949-952.

14. Liu, M.C.; Hyder, Z.; Sun, Y.W.; Tang, W.J.; Xu, L.J. and Xiao, J.L. "Efficient synthesis of alkyl aryl ketones & ketals via palladium-catalyzed regioselective arylation of vinyl ethers", Org. Biomol. Chem. 2010, 8, 2012-2015.

13. Lam, K.; Gambari, R.; Yuen, M.; Kan, C.; Chan, P.; Xu, L.; Tang, W.J.;et.al,"The preparation of 2,6-disubstituted pyridinyl phosphine oxides as novel anti-cancer agents", Bioorg.  Med. Chem. Lett. 2009, 19, 2266-2269.

12. Xu, D.; Liu, Z.H.; Tang, W.J.; Xu, L.J.; Hyder, Z.; Xiao, J.L.   "Palladium-catalyzed regiocontrolled internal heteroarylation of electron-rich olefins with heteroaryl halides", Tetrahedron Lett. 2008, 49, 6104-6107. 

11. Liu, Z.H.; Xu, D.; Tang, W.J.; Xu, L.J.; Mo, J.; Xiao, J.L. "A general method for regioselective Heck arylation of electron-rich N-acyl-N-vinylamine with aryl halides", Tetrahedron Lett. 2008, 49, 2756–2760.

10. Xu, D.; Liu, Z.H.; Tang, W.J.; Mo, J.; Xu, L.J. "Palladium-catalyzed highly regioselective Heck reaction of aryl nonaflates with electron-rich olefins", Chinese Chemical Letters, 2008, 19,1017-1020.

9. Chan, S.H.; Lam, K.H.; Li, Y.M.; Xu, L.J.; Tang, W.J.;Lam, F.L.; Lo, W.H.; Yu, W.Y.; Fan, Q.H. and Albert S. C. Chan, "Asymmetric hydrogenation of quinolines with recyclable and air-stable iridium catalyst systems", Tetrahedron: Asymmetry 2007, 18, 2625-2631.

9. Wang, Z.J.; Deng, G..J.; Li, Y.; He, Y.M.; Tang, W.J.; Fan, Q.H. "Enantioselective hydrogenation of quinolines catalyzed by Ir(BINAP)-Cored dendrimers: Dramatic enhancement of catalytic activity", Org. Lett. 2007, 9, 1243-1246. 

8. Zhou, H.F.; Fan,Q.H.; Huang, Y.Y.; Wu, L.; He, Y.M.; Tang, W.J.; Gu, L.Q. and Albert S. C. Chan. "Mixture of poly(ethylene glycol) and water as environmentally friendly media for efficient enantioselective transfer hydrogenation and catalyst recycling", J. Mol. Catal. A: Chem. 2007, 275, 47-53.

7. Zhou, H.F.; Fan,Q.H.; Tang,W.J.; Xu,L.J.; He,Y.M.; Deng, G.J.; Zhao, L.W.; Gu, L.Q. and Albert S. C. Chan."Polyethylene Glycol as an Environmentally Friendly and Recyclable Reaction Medium for Enantioselective Hydrogenation", Adv. Synth. Catal. 2006, 348, 2172-2182.

6. Zhang, Y.L.; Zhang, F.; Tang, W.J.; Wu, Q.L.; Fan, Q.H. "Synthesis and Application of 3,3'-Diarylmethyl BINOLs", Synlett, 2006, 1250-1254. 

 5. Yang, N.F.; Gong, H.; Tang, W.J.; Fan, Q.H.; Cai, C.Q.; Yang, L.W. "Phase selectively soluble dendritic derivative of 4-(N,N-dimethylamino)pyridine: an easily recyclable catalyst for Baylis–Hillman reactions", J. Mol. Catal. A: Chem. 2005, 233, 55-59.

4. Gong, H.; Yang, N.F.; Tang, W.J.; Fan, Q.H.; Yang, L.W. "Phase Selectively Soluble Dendritic Derivative of 4-(Dimethylamino) -pyridine: An Easily Recyclable Catalyst for Baylis-Hillman Reactions", Chinese Chemical Letters 2005, 16, 1017-1020.

3. Huang, Y.Y.; Zhang, H.L.; Deng, G.J.; Tang, W.J.; Wang, X.Y.; Fan, Q.H. "Synthesis of triphenylphosphine-functionalized dendrimers and application to olefin hydroformylation", J. Mol. Catal. A: Chem. 2005, 227, 91-96.

2. Deng, G.J.; Yi, B.; Huang, Y. Y.;Tang, W.J.; He, Y.M.; Fan, Q.H. "Dendrinized  poly(Ru-BINAP) complexes: a highly effective and easily recyclable catalyst for asymmetric hydrogenation", Adva. Synth. Catal. 2004, 346, 1440-1444. (wiley publishing)

1. Liu, G.H.; Tang, W.J. and Fan, Q.H. "Dendritic BINOL ligands for asymmetric catalysis: effect of the linking positions and generations of the dendritic wedges on catalyst properties", Tetrahedron 2003, 59, 8603-8611.