张军研究员简介
| 张军 研究员,博士生导师,国家杰出青年基金获得者 1999年获大连理工大学工学博士学位。1999-2001年,在中科院化学所工程塑料实验室从事博士后研究工作;2001年至今,在中科院化学所工程塑料重点实验室工作,先后任副研究员,项目研究员,课题组长,研究员。近年来,先后承担的重要科研项目包括:国家科技支撑计划重大专项1项,863项目1项,国家973项目子课题2项,国家自然基金项目5项,中国科学院知识创新工程重要方向项目3项,国家大型企业合作项目2项。已在国内外重要专业期刊上发表论文120余篇,发表论文被SCI引用超过2800余次。申请中国发明专利20项,获授权15项。参与撰写专著三部。多次应邀在国内外高分子材料相关领域的国际学术会议上做邀请报告。获2013年度北京市科学技术一等奖和2008年度北京市科学技术二等奖,目前担任中国纤维素行业协会(CCIA)技术专家委员会副主任,中国科学院分子科学中心学术委员会委员,北京市纤维素及其衍生材料工程技术研究中心学术委员会委员,国际聚合物专业期刊《Polymer International》(Wiley)和《高分子学报》编委。 目前主要研究兴趣包括:天然高分子的加工与改性;纤维素化学与物理;离子液体在高分子材料中的应用;聚合物共混物与聚合物复合材料;新型聚合物纤维等。
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发表论文
1. 栾贻浩, 武进, 詹茂盛, 张金明, 张军, 何嘉松. "一锅法"均相合成热塑性纤维素丙酸酯接枝聚乳酸共聚物, 高等学校化学学报, 2012, 33(10): 2135-2137 |
2. Tong FF, Xu H, Yu J, Wen LX, Zhang J, He JS. Plasticization of [C12MIM][PF6] Ionic Liquid on Foaming Performance of Poly(methyl methacrylate) in Supercritical CO2. Ind & Eng Chem Res, 2012, 51 (38): 12329-12336 |
3. Liu FY, Li FY, Deng GH, Chen YM, Zhang BQ, Zhang J, Liu CY. Rheological Images of Dynamic Covalent Polymer Networks and Mechanisms behind Mechanical and Self-Healing Properties. Macromolecules, 2012, 45, 1636−1645 |
4. Xu H, Tong FF, Yu J, Wen LX, Zhang J, He JS. A one-pot method to prepare transparent poly(methyl methacrylate)/montmorillonite nanocomposites using imidazolium-based ionic liquids. Polym Int 2012, 61: 1382–1388 |
5. Luo N, Lv YX, Wang DX, Zhang JM, Wu J, He JS, Zhang J. Direct visualization of solution morphology of cellulose in ionic liquids by conventional TEM at room temperature. Chem. Commun., 2012, 48, 6283–628 |
6. Luo N, Varaprasad K, Reddy GVS, Rajulu AV, Zhang J. Preparation and characterization of cellulose/curcumin composite films. RSC Advances, 2012, 2, 8483–8488 |
7. Lv YX, Wu J, Zhang JM, Niu YH, Liu CY, He JS, Zhang J. Rheological properties of cellulose/ionic liquid/dimethylsulfoxide (DMSO) solutions. Polymer, 2012, 53, 2524-2531 |
8. 仝芳芳, 徐鸿, 余坚, 文利雄, 张军, 何嘉松. 相容的聚甲基丙烯酸甲酯/[C12 MIM][PF6]离子液体体系在超临界CO2中的发泡性能. 高等学校化学学报, 2012, 33(01): 172-175 |
9. Wang YB, Yang L, Niu YH, Wang ZG, Zhang J, Yu FY, Zhang HB. Rheological and Topological Characterizations of Electron Beam Irradiation Prepared Long-Chain Branched Polylactic Acid. J Appl. Polym. Sci., 2011, 122(3):1857-1865 |
10. Cao Y, Li HQ, Zhang J. Homogeneous Synthesis and Characterization of Cellulose Acetate Butyrate (CAB) in 1-Allyl-3-Methylimidazolium Chloride (AmimCl) Ionic Liquid. Ind Eng Chem Res 2011, 50 (13): 7808-7814 |
11. Song HZ, Niu YH, Wang ZG, Zhang J. Liquid Crystalline Phase and Gel-Sol Transitions for Concentrated Microcrystalline Cellulose (MCC)/1-Ethyl-3-methylimidazolium Acetate (EMIMAc) Solutions. Biomacromolecules, 2011, 10(2):1087-1096 |
12. Lan QF, Yu J, Zhang J, He JS. Enhanced Crystallization of Bisphenol A Polycarbonate in Thin and Ultrathin Films by Supercritical Carbon Dioxide. Macromolecules, 2011, 44 (14): 5743-5749 |
13. 张金明,张军. 基于纤维素的先进功能材料, 高分子学报,2010,12:1376-1398 |
14. 李博轩,余坚,丁运生,张军,何嘉松. [C14MIM]Br离子液体对聚丙烯超临界CO2发泡性能的影响.高等学校化学学报.2010, 31(5):861-863 |
15. Song HZ, Zhang J, Niu YH, Wang ZG. Phase Transition and Rheological Behaviors of Concentrated Cellulose/Ionic Liquid Solutions. J Phys Chem B, 2010, 114, 6006–6013 |
16. Zhang BQ, Ning W, Zhang JM, Qiao X, Zhang J, He JS, Liu CY. Stable dispersions of reduced graphene oxide in ionic liquids. J Mate Chem, 2010, 20, 5401–5403 |
17. Li XY, Zhang J, He JS, Reddy DJP, Rajulu AV. Tensile Properties of Hildegardia Fibers Reinforced Polypropylene Biocomposites. J Compos Mater, 2010, 44(14):1681-1687 |
18. Cao Y, Zhang J, He J, Li HQ, Zhang Y. Homogeneous Acetylation of Cellulose at Relatively High Concentrations in an Ionic Liquid. Chinese J Chem Eng, 2010, 18(3): 515-522 |
19. Cao Y, Li HQ, Zhang Y, Zhang J, He JS. Structure and Properties of Novel Regenerated Cellulose Films Prepared from Cornhusk Cellulose in Room Temperature Ionic Liquids. J. Appl. Polym. Sci.,2010, 116 (1): 547- 554 |
20. Zhang JM, Zhang H, Wu J, Zhang J, He JS, Xiang JF. Reply to ‘‘Comment on ‘NMR spectroscopic studies of cellobiose solvation in EmimAc aimed to understand the dissolution mechanism of cellulose in ionic liquids’’’ by R. C. Remsing, I. D. Petrik, Z. Liu and G. Moyna, Phys. Chem. Chem. Phys., 2010, 12, DOI: 10.1039/c004203j. Phys Chem Chem Phys, 2010,12, 1941-1947 |
21. Zhang JM, Zhang H, Wu J, Zhang J, He JS, Xiang JF. NMR spectroscopic studies of cellobiose solvation in EmimAc aimed to understand the dissolution mechanism of cellulose in ionic liquids. Phys Chem Chem Phys, 2010,12, 1941-1947 |
22. Yan CH, Zhang JM, Lv YX, Yu J, Wu J, Zhang J, He JS. Thermoplastic Cellulose-graft-poly(L-lactide) Copolymers Homogeneously Synthesized in an Ionic Liquid with 4-Dimethylaminopyridine (DMAP) Catalyst. Biomacromolecules, 2009, 10(8):2013-2018 |
23. Zhang JM, Wu J, Cao Y, Sang SM, Zhang J, He JS. Synthesis of cellulose benzoates under homogeneous conditions in an ionic liquid. Cellulose,2009, 16:299-308 |
24. Meng T, Gao X, Zhang J, Yuan JY, Zhang YZ, He JS, Graft Copolymers prepared by Atom Transfer Radical Polymerization (ATRP) from Cellulose. Polymer, 2009, 50(2):447-454 |
25. Cao Y, Wu J, Zhang J, Li HQ, Zhang Y, He JS. Room Temperature Ionic Liquids (RTILs): A New,Versatile Platform for Cellulose Processing and Derivatization. Chem Eng J. 2009, 147(1):13-21 |
26. 曹妍, 李会泉, 张懿, 张军, 何嘉松. 低取代醋酸纤维素的均相合成及其水溶性. 高等学校化学学报, 2008, 29 (10): 2115-2117 |
27. Sui XF, Yuan JY, Zhou M, Zhang J,Yang HJ, Yuan WZ, Wei Y, Pan CY. Synthesis of Cellulose-graft-Poly(N,N-dimethylamino-2-ethyl methacrylate) Copolymers via Homogeneous ATRP and Their Aggregates in Aqueous Media. Biomacromolecules,2008, 9, 2615–2620 |
28. Xiang L, Zhang ZN, Yu P, Zhang J, Su L, Ohsaka T, Mao LQ. In Situ Cationic Ring-Opening Polymerization and Quaternization Reactions To Confine Ferricyanide onto Carbon Nanotubes: A General Approach to Development of Integrative Nanostructured Electrochemical Biosensors. Anal. Chem.2008, 80, 6587–6593 |
29. Kuang QL, Zhao JC, Niu YH, Zhang J, Wang ZG. Celluloses in an Ionic Liquid: the Rheological Properties of the Solutions Spanning the Dilute and Semidilute Regimes. J. Phys. Chem. B,2008, 112, 10234–10240 |
30. Yu P, Yan J, Zhao H, Su L, Zhang J, Mao LQ. Rational functionalization of carbon nanotube/ionic liquid bucky gel with dual tailor-made electrocatalysts for four-electron reduction of oxygen. J Phys Chem C, 2008, 112 (6): 2177-2182 |
31. Xu SS, Zhang J, He AH, Li JX, Zhang H, Han CC. Electrospinning of native cellulose from nonvolatile solvent system. Polymer,2008, 49: 2911–2917 |
32. Zhang H, Wang ZG, Zhang ZN, Wu J, Zhang J, He JS. Regenerated Cellulose/Multi-Walled Carbon Nanotube (MWCNT) Composite Fibers with Enhanced Mechanical Properties Prepared with an Ionic Liquid 1-Allyl-3-methylimidazolium Chloride (AmimCl). Adv Mater, 2007, 19(5):698-704 |
33. Cao Y, Wu J, Meng T, Zhang J,He JS, Li HQ, Zhang Y. Acetone-soluble cellulose acetates prepared by one-step homogeneous acetylation of cornhusk cellulose in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl). Carbohydrate Polym,2007, 69: 665–672 |
34. Kuang QL, Zhang J, Wang ZG, Revealing Long-Range Density Fluctuations in Dialkylimidazolium Chloride Ionic Liquids by Dynamic Light Scattering,J. Phys. Chem. B,2007, 111 (33): 9858-9863 |
35. Ding YS, Zha M, Zhang J, Wang SS. Synthesis, characterization and properties of geminal imidazolium ionic liquids. Colloids Surf A-Physicochem Eng Aspects, 2007, 298 (3): 201-205 |
36. Ding YS, Zha M, Zhang J, Wang SS. Synthesis of a kind of gerninal imidazolium ionic liquid with long aliphatic chains. Chinese Chem Lett,2007, 18 (1): 48-50 |
37. Chen J, Chen P, Wu LC,Zhang J, He JS. Fibrillation of liquid crystalline polymer in polysulfone promoted by increased system elasticity via adding nano-silica.Polymer, 2007, 48 (14): 4242-4251 |
38. Liao X, He JS, Zhang J, Ma WM. Effect of cosolvent on solid phase transitions of alpha- to beta-form crystal of syndiotactic polystyrene occurred in supercritical CO2 containing solvent. J Polym Sci, Part B-Polym Phys, 2007, 45 (13): 1625-1636 |
39. Wu LC, Chen P, Chen J, Zhang J, He JS. Noticeable viscosity reduction of polycarbonate melts caused jointly by nano-silica filling and TLCP fibrillation. Polym Eng Sci,2007, 47 (6): 757-764 |
40. Chen J, Chen P, Wu L, Zhang J, He J. Effect of aspect ratio of whisker on the fibrillation of liquid crystalline polymer in polysulfone matrix. Inter Polym Proc, 2007, 22 (2): 166-172 |
41. 周巧萍,武进,张军,何嘉松,孙志杰,张佐光.高直链淀粉乙酸酯的合成及其静电纺丝. 高分子学报,2007,7:685-688 |
42. Xia Jiqiang; Zhang Jun; Liao Gongxiong. Et al Copolymerization and blending of poly(phthalazinone ether ketone)s to improve their melt processability. J Appl Polym Sci,2007, 103(4): 2575-2580 |
43. Wu J, Zhang H, Zhang J, He JS. Homogeneous acetylation and regioselectivity of cellulose in a new ionic liquid. Chem. J. Chin. Univ.-Chin., 2006, 27 (3): 592-59 |
44. Zhang ZN, Zhang J*, Chen, P, Zhang BQ, He JS*, Hu, GH. Enhanced interactions between multi-walled carbon nanotubes and polystyrene induced by melt mixing. Carbon,2006, 44 (4): 692-698 |
45. Chen J, Chen P, Wu LC, Zhang J, He JS. Enhanced fibrillation of LCP by CaCO3 whisker in polysulfone matrix through increasing elongational stress. Polymer,2006, 47 (15): 5402-5410 |
46. Chen P, Wu LC, Ding YF, Zhang J, He JS. Morphology evolution of a liquid crystalline polymer in polycarbonate matrix enhanced by the addition of glass beads. Compos. Sci. Technol.,2006, 66 (11-12): 1564-1574 |
47. Ding YF, He JS, Zhang J,Liu CY, Chen P, Zhang AQ. Rheological hybrid effect in nylon 6/liquid crystalline polymer blends caused by added glass beads. J. Non-Newton. Fluid Mech., 2006, 135 (2-3): 166-176 |
48. Li G, Sun XH, Liao X, Yu J, Zhang J, He JS. Supercritical carbon dioxide assisted preparation of conductive polypyrrole/cellulose diacetate composites. J. Appl. Polym. Sci.,2006, 100 (6): 4575- 4580 |
49. Zheng W, Li QF, Su L, Yan YM, Zhang J, Mao LQ. Direct electrochemistry of multi-copper oxidases at carbon nanotubes noncovalently functionalized with cellulose derivatives. Electroanalysis, 2006, 18 (6): 587-594 |
50. Chen P, Chen J, Zhang BQ,Zhang J, He JS. Effect of glass bead packing on the fibrillation of liquid-crystalline polymer in polycarbonate. J. Polym. Sci. Pt. B-Polym. Phys., 2006, 44 (6): 1020-1030 |
51. Wu LC, Chen P, Zhang J, He JS. Inhibited transesterification and enhanced fibrillation of TLCP by nano-SiO2 in polycarbonate matrix. Polymer, 2006, 47 (1): 448-456 |
52. Zhang H, Wu J, Zhang J, He JS. 1-Allyl-3-methylimidazolium chloride room temperature ionic liquid: A new and powerful nonderivatizing solvent for cellulose. Macromolecules, 2005, 38 (20): 8272-8277 |
53. Yu P, Lin YQ, Xiang L, Su L, Zhang J, Mao LQ. Molecular films of water-miscible ionic liquids formed on glassy carbon electrodes: Characterization and electrochemical applications Langmuir ,2005, 21 (20): 9000-9006 |
54. Zhang BQ, Ding YF, Chen P, Liu CY,Zhang J, He JS, Hu GH. Fibrillation of thermotropic liquid crystalline polymer enhanced by nano-clay in nylon-6 matrix .Polymer,2005, 46 (14): 5385-5395 |
55. Chen P, Zhang J, He JS. Increased flow property of polycarbonate by adding hollow glass beads. Polym Eng Sci,2005,45 (8):1119-1131 |
56. Ding YF, Zhang J, Chen P, Zhang BQ, Yi ZQ, He JS. Hierarchical structure of thermotropic liquid crystalline polymer formed in blends jointly by dynamic and thermodynamic driving forces. Polymer, 2004, 45 (23): 8051-8058 |
57. Wu J,Zhang J, Zhang H, He JS, Ren Q, Guo M. Homogeneous acetylation of cellulose in a new ionic liquid. Biomacromolecules, 2004,5 (2): 266-268 |
58. Liu CY, Zhang J, He JS, Hu GH. Gelation in carbon nanotube/polymer composites. Polymer,2003, 44 (24): 7529-7532 |
59. Ren Q, Wu J, Zhang J, He JS, Guo ML. Synthesis of 1-allyl,3-methyle mazolium-based room temperature ionic liquid and preliminary study of its dissolving cellulose. Acta Polym Sin.2003, (3): 448-451 |
60. Yujun Qin, Luqi Liu, Jiahua Shi, Wei Wu, Jun Zhang, Zhi-Xin Guo, Yongfang Li, and Daoben Zhu. Large-Scale Preparation of Solubilized Carbon Nanotubes. Chem. Mater. 2003, 15, 3256-3260 |